What happens is that as you get near the capacitors rated voltage the leakage current increases significantly. I used to say to go double the expected highest voltage for electrolytic capacitors.

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The voltage rating is just an upper limit which must never be exceeded in a functional circuit.

Electrolytic capacitor higher voltage. Not to mention if a higher voltage has reached the capacitor its likely in other places on the board. Youd be ok to select a cap with a voltage rating 20 higher than expected. Replacing a capacitor with something that has a higher voltage rating is always safe.
However due to standardized safety margins the actual forming voltage of electrolytic capacitors is higher than the rated voltage of the component. Silver mica disc and line filter safety capacitors also for sale. Electrolytic capacitors and film capacitors have high voltages and long radial or axial leads ideal for antique tube radio repairs.
Sells high voltage capacitors for tube radio restorations. Thus the dielectric strength also influences the size of the capacitor. One common rule of thumb for the balancing current is 10x the leakage current thus for two 100uf350v capacitors connected in series to form a 50uf capacitor maximum leakage of 12 sqrt 100350 94ua times 10 is about 1 ma.
A high voltage would probably get through the board one way or the other. Other high voltage capacitors for tube radios. The only problem there is that a capacitor rated for a higher voltage is often physically larger everything else being equal.
Aluminum anode foils are manufactured as so called mother rolls of about 500 mm in width. Capacitors are generally placed in parallel with other paths in the circuit. Lets say we want our applied voltage to be 650v then rb1 and rb2 325k ohms.
Electrolytic capacitors should be operated no more than 75 of maximum working voltage to prolong operating life and allow some margin of safety for unexpected voltage surges. For aluminum electrolytic capacitors with a rated voltage of up to 315 v the surge voltage is 115 times the rated voltage and for capacitors with a rated voltage exceeding 315 v the surge voltage is 110 times the rated voltage.

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